Konstantin I. Matveev, Jacob W. Leachman

Abstract: Raising efficiency of the cooling process for cryogenic hydrogen and minimizing hydrogen boil-off during storage and transportation of liquid hydrogen are critically important factors for widening implementation of hydrogen-based clean energy systems. One novel approach involves utilization of relatively simple catalyzed vortex tubes, where hydrogen in the primarily para- nuclear spin isomer form is converted into the ortho- form while consuming a significant amount of heat. To design such systems effectively, better understanding is required about catalyst-assisted para-orthohydrogen conversion rates in high-speed vortical flows. In this study, a computational fluid dynamics simulation has been set up to model an experimental system with cryogenic hydrogen vortex tubes. Mesh-verification and a validation study has been conducted first for a non-catalyzed tube. Then, the rate coefficient of the para-orthohydrogen conversion of cryogenic hydrogen has been determined by matching numerical results with experimental data available for a catalyzed vortex tube. The presented information can help design and optimize cryogenic hydrogen cooling within vortex tubes.

Keywords: Vortex tubes, Hydrogen systems, Para-orthohydrogen conversion, Cryogenics, Computational fluid dynamics.

Date Published: June 16, 2023
DOI: 10.11159/jffhmt.2023.003

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